Angew Chem Int Ed 49:8984–8987, Zeng XM, Soleilhavoup M, Bertrand G (2009) Gold-catalyzed intermolecular markovnikov hydroamination of allenes with secondary amines. You’ve supercharged your research process with ACS and Mendeley! Metal-catalyzed regiodivergent organic reactions. Finally, tandem hydroamination/carbocyclization reactions of aminodialkenes provide rapid access to complex alkaloidal skeletons. Catalysis by 1,2,3-triazole- and related transition-metal complexes. The Bonding Nature of Cyclometalated Ru Complex: How DFT Study Revealing the Dewar-Chatt-Duncanson Model Relates to the Molecular Properties. Asymmetric intermolecular hydroamination of 1-alkenes with a primary amine. Catalysts that include electropositive elements such as alkali, alkaline earth, and rare earth metals typically operate through a metal-amido species that undergoes nucleophilic addition to the alkene (Eq. The addition of an amine NH‐functionality to alkenes (including vinyl arenes, conjugated dienes, allenes or ring‐strained alkenes), the so‐called hydroamination, represents a simple and highly atom‐economical approach for the synthesis of nitrogen‐containing products. Dr. Xiaohong Hu was born in Jingdezhen, Jiangxi China, in 1964. )-catalysed [1,3] O→C rearrangement of allenyl ethers. Information. Theoretical insight into the Au(
Finally, tandem hydroamination/carbocyclization reactions of aminodialkenes provide rapid access to complex alkaloidal skeletons. The results indicate that the reaction cycle proceeds via a Ti–imido–amido complex as the catalytically active species. Arianna Antonucci, Mauro Bassetti, Christian Bruneau, Pierre H. Dixneuf, and Chiara Pasquini . The addition of an amine NH‐functionality to alkenes (including vinyl arenes, conjugated dienes, allenes or ring‐strained alkenes), the so‐called hydroamination, represents a simple and highly atom‐economical approach for the synthesis of nitrogen‐containing products. He received his Ph.D. degree in 2013 from the State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, working under the direction of Prof. Taicheng An. Mu-Jeng Cheng, Robert J. Nielsen, Mårten Ahlquist and William A. Goddard, III. Angew Chem Int Ed 131:3416–3419, Vanable EP, Kennemur JL, Joyce LA, Ruck RT, Schultz DM, Hull KL (2019) Rhodium-catalyzed asymmetric hydroamination of allyl amines. The author speculated that the formation of trans Pt-C bond by platinum hydride, is conducive to the deprotonation and get good yield. The addition of amines to slightly activated alkenes, such as vinyl arenes, 1,3‐dienes, strained alkenes (norbornene derivatives, methylenecyclopropenes) and allenes is closely related and is covered as well. Google Scholar, Ryabchuk P, Agostini G, Pohl M-M, Lund H, Agapova A, Junge H, Junge K, Beller M (2018) Intermetallic nickel silicide nanocatalyst-A non-noble metal-based general hydrogenation catalyst. Information about how to use the RightsLink permission system can be found at Rajashekharayya A. Sanguramath, Thomas N. Hooper, Craig P. Butts, Michael Green, John E. McGrady, Christopher A. Russell. Use the link below to share a full-text version of this article with your friends and colleagues. Some articles have been published on Catal. The Origin of Anti-Markovnikov Regioselectivity in Alkene Hydroamination Reactions Catalyzed by [Rh(DPEphos)]
Christophe Michon, Florian Medina, Marc-Antoine Abadie, and Francine Agbossou-Niedercorn . Ming-Zhong Wang, Cong-Ying Zhou, Zhen Guo, Ella Lai-Ming Wong, Man-Kin Wong, Chi-Ming Che. Gold-Gold Cooperation in the Addition of Methanol to Alkynes. One-Pot Procedure for the Synthesis of
It has been shown that the synthesized series of compounds have antifungal activity. Gold(I)-Catalyzed Enantioselective Intermolecular Hydroarylation of Allenes with Indoles and Reaction Mechanism by Density Functional Theory Calculations. Chem., RSC adv., Appl. New Highly Active Heteroscorpionate-Containing Lutetium Catalysts for the Hydroamination of Aminoalkenes: Isolation and Structural Characterization of a Dipyrrolidinide–Lutetium Complex. Jeremy M. Hines, Jesse J. Eason, and Matthew R. Siebert . Ghanem Hamdoun, Christophe Bour, Vincent Gandon. Cecilia Mariel Gallego, Carina Gaviglio, Yehoshoa Ben-David, David Milstein, Fabio Doctorovich, Juan Pellegrino. If you do not receive an email within 10 minutes, your email address may not be registered,